Composition tunable ternary Pt-Ni-Co octahedra for optimized oxygen reduction activity.

نویسندگان

  • Zipeng Zhao
  • Miao Feng
  • Jihan Zhou
  • Zeyan Liu
  • Mufan Li
  • Zheng Fan
  • Oshton Tsen
  • Jianwei Miao
  • Xiangfeng Duan
  • Yu Huang
چکیده

Herein, we report a one-step synthesis method for octahedral Pt-Ni-Co ternary catalysts with tunable compositions and fixed shapes. Impressively, the composition optimized octahedral PtNi0.55Co0.1/C demonstrated a significant improvement in ORR activity compared to those of previously reported Pt-Ni-Co alloy octahedra, showing an outstanding specific activity of 5.05 mA cm-2 and a mass activity of 2.80 mA μgPt-1, which are around 20.2 times and 14.7 times higher than those of the commercial Pt/C catalyst (0.25 mA cm-2 and 0.19 mA μgPt-1).

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عنوان ژورنال:
  • Chemical communications

دوره 52 75  شماره 

صفحات  -

تاریخ انتشار 2016